✦ LIBER ✦

Thermal reactions of azidoformates

✍ Scribed by T.J. Prosser; A.F. Marcantonio; C.A. Genge; D.S. Breslow

Book ID: 104212134
Publisher: Elsevier Science
Year: 1964
Tongue: French
Weight: 203 KB
Volume: 5
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)70412-6

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✦ Synopsis

In the past several years, there has been considerable interest in the chemistry of azidoformates.

In 1962,

Liiowski and Mattingly (1) reported that the photolysis of ethyl azidoformate in cyclohexene gives 7-carbethoxy-7-azabicyclo LT.1.2, heptsne, while under the same conditions in cyclohexane the major product is N-cyclohexylurethane.

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