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Thermal decomposition of methyl diazoacetate and azidoformate in vinyl sulfides. IV.

✍ Scribed by Wataru Ando; Hitoshi Fujii; Tetsuo Takeuchi; Hirofumi Higuchi; Yoshio Saiki; Toshihiko Migita

Book ID: 104238157
Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 184 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)86822-2

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✦ Synopsis

We have already reported that carbene and nitrene react with sulfur compounds to afford the corresponding sulfonium ylides I,2 and iminosulfuranes 3.4 , and with allylic sulfides, these reactive species attack a sulfur atom 2.5-5 times more rapidly than the carbon-carbon double bond, and the main reaction

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