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Thermal properties of some di(4-substituted phenyl)tin dichloride complexes with nitrogen donor ligands

✍ Scribed by B N Biddle; J S Gray; G P Ormiston

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 337 KB
Volume: 2
Category: Article
ISSN: 0268-2605
DOI: 10.1002/aoc.590020510

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✦ Synopsis

The thermal properties of some organotin complexes of general structure (4-ZC6H,),SnCl,.L, (Z=Me, CF,, F, C1, OMe and H; L, = 2,2 '-bipyridyl and 4,4'-dimethyl-2,2 '-bipyridyl) are reported. The thermal data obtained by Differential Thermal Analysis (DTA) for these complexes is reported. Thermal decomposition experiments for some of the complexes are described and indicate a disproportionation of the complexes into the aryltin trichloride complex and the triaryltin chloride. The controlled decomposition provides a possible alternative preparative route to some aryltin trichloride complexes.

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