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Thermal parameters of 11,11-dimethyltricyclo [4,4,1,01,6] undeca-2,4,7,9-tetraene: A lattice-dynamical discussion

✍ Scribed by Giuseppe Filippini; Carlo M. Gramaccioli; Massimo Simonetta; Giuseppe B. Suffritti


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
333 KB
Volume
26
Category
Article
ISSN
0009-2614

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✦ Synopsis


An unusual C-C bond length (1.81 A) is observed in a derivative of [ 101 annulrne; a possibility of cocsistence of two different isomers in the same crystal structure is definitely ruled out by a lattice-dynamical analysis of thermal motion.


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## Abstract The deformation density and potential have been determined in molecular crystals of tricyclo[4.4.1.0^1,6^]ndeca‐2,4,7,9‐tetraene‐11,11‐dicarbonitrile at 150 K from X‐ray diffraction measurements. A significant degformation density peak is found near the mid‐poind of the the transannular