The Berson-Willcott Rearrangement of 11,11-Dimethyltricyclo[4.4.1.01,6]undeca-2,4,7,9-tetraene and Its Radical Anion
✍ Scribed by Prof. Dr. Fabian Gerson; Dipl.-Chem. Walter Huber; Priv.-Doz. Dr. Klaus Müllen
- Publisher
- John Wiley and Sons
- Year
- 1978
- Tongue
- English
- Weight
- 226 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The deformation density and potential have been determined in molecular crystals of tricyclo[4.4.1.0^1,6^]ndeca‐2,4,7,9‐tetraene‐11,11‐dicarbonitrile at 150 K from X‐ray diffraction measurements. A significant degformation density peak is found near the mid‐poind of the the transannular
Dehalogenation of the mixed anhydride 6 of 11-bromotricyclo[4.4.1 .0',6]undeca-3,8-diene-l 1-carboxylic acid (4) and of diethyl hydrogen phosphate with Zn-Ag couple in THF gave the dispiro-fused dipropellane 8 ( I , l", 4,4,5,5", 8,8"-octahydrodispiro[[4a, 8a]methanonaphthalene-9,1 '-cyclobutane-3',