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Thermal low spin–high spin equilibrium of Fe(II) in thiospinels CuFe0.5(Sn(1−x)Tix)1.5S4 (0≤x≤1)

✍ Scribed by M. Womes; C. Reibel; A. Mari; D. Zitoun


Book ID
108195862
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
764 KB
Volume
184
Category
Article
ISSN
0022-4596

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High spin (5T2)-low spin (1A1) equilibri
✍ M. Womes; J.-C. Jumas; J. Olivier-Fourcade; F. Aubertin; U. Gonser 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 324 KB

The compounds M2FeSn& (M=Cu, Ag) represent, to our knowledge, the first example ofan iron(I1) high spin ('T2) -low spin ('A, ) transition in the spine1 lattice. Additionally, these compounds are one of the rare caSes where such a spin transition is observed for bivalent iron in an octahedral sulfur