High spin (5T2)-low spin (1A1) equilibri
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M. Womes; J.-C. Jumas; J. Olivier-Fourcade; F. Aubertin; U. Gonser
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Article
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1993
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Elsevier Science
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English
⚖ 324 KB
The compounds M2FeSn& (M=Cu, Ag) represent, to our knowledge, the first example ofan iron(I1) high spin ('T2) -low spin ('A, ) transition in the spine1 lattice. Additionally, these compounds are one of the rare caSes where such a spin transition is observed for bivalent iron in an octahedral sulfur