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Nature of the continuous high-spin (5T2) .dblharw. low-spin (1A1) transition in bis[2-[(4-methyl-2-pyridyl)amino]-4-(2-pyridyl)thiazole]iron(II) diperchlorate dihydrate and bis(tetrafluoroborate) dihydrate: Moessbauer effect and x-ray diffraction study

✍ Scribed by Koenig, E.; Ritter, G.; Kulshreshtha, S. K.; Goodwin, H. A.


Book ID
127075067
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
765 KB
Volume
22
Category
Article
ISSN
0020-1669

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📜 SIMILAR VOLUMES


Thermally induced high-spin (5T2) ⇌ low-
✍ E. König; G. Ritter; H.A. Goodwin 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 403 KB

Employmg snmplcs cnrichcd to >90% in 57Fc, hlbssbducr cffcct studlcs dcmonstratc that high-spin (%2) := low-spm ('A1) transitions arc responsible for the peculiar tempcraturc dcpendcncc of the mdgnctlsm in ccrtam [fc(paptH)z ] X2 l nH20 complcxcs where paptH = 2-(2-pyridyhho) -4-(2-pyrldyl)thiai!olc