The absolute quantum yield of the photosensitized luminescence from lag 0 2 has been measured in air-saturated solutions of tetraphenylporphin in CC14, the value (4.4 + 1.3) X 10 -3 being obtaified. The radiative lifetime of lAg O 2 is approximately constant in all solvents investigated and is 4.1 -
Thermal-lensing measurements of singlet molecular oxygen (1Δg): Quantum yields of formation and lifetimes
✍ Scribed by Gerald Rossbroich; Norman A. Garcia; Silvia E. Braslavsky
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 875 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0047-2670
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The quantum yield for the O2 '$-+%g radiative transition was determined in benzene by comparison of the singlet oxygen phosphorescence at 1275 nm, sensitized by 9,1O\_dicyanoanthracene, with the fluorescence of five different dyes emitting in the same spectral region. A value of Qp= (2.5+ 1.3) x 10m
It was possible to measure the phosphorescence of singlet oxygen ('0,) sensitized by tctraphenylporphinc (TPP) by means of a sensitive pyroelectric radiometer. The IO2 phosphorescence quantum yield was determined directly by comparison of the intensities of the spectrally unresolved emissions of '02
nevertheless t h e y are extractable by o t h e r organic s o l v e n t s such as hexane or petrol ether that are commonly used to o b t a i n e "sansa" olive oil from pomace, and seed oils as well. These considerations should make it plain that olive oil obtained by the simple physical procedures
The absolute quantum yields, QAd, of photosensitized formation of singlet molecular oxygen, O2 (I$), by various sensitizers in benzene were measured by time-resolved thermal lensing (TRTL). Relative measurements with time-resolved O,( 'Ag) phosphorescence detection were used to confirm the absolute