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Thermal isomerization of isopropyl radicals

✍ Scribed by Szirovicza, I. ;Márta, F.

Book ID
112711041
Publisher
Springer
Year
1975
Tongue
English
Weight
191 KB
Volume
3
Category
Article
ISSN
0133-1736

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📜 SIMILAR VOLUMES

Some reactions of the isopropyl radical
Some reactions of the isopropyl radical
✍ L. Szirovicza; F. Márta 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 574 KB

The decomposition of ethane sensitized by isopropgl radicals was studied in the tempera- The rate of formation of n-butane, isopentane, and 2,S-dimethyl-t,iire range of 496-548°K. butane were nieasrued. The expression kI/PZ1'\* was found to be log kl/kg"2(dm3'\*/n~ol"2 . see1!\*) = (3.2 f 0.4) -(54

Isomerization of unsaturated radicals. V
Isomerization of unsaturated radicals. V. Unimolecular isomerization of hot α,α- and α,β-dimethallyl radicals
✍ Hélêne Deslauriers; Guy J. Collin 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 434 KB

The 147 nm photolysis of 3,3 dimethylbut-l-ene leads mainly to the formation of very hot ( ~3 7 5 kJ/mol) a,a-dimethallyl radicals. On the other hand, that of 3-methyl-cisand trans-pentene-2, as well as that of 2,3-dimethylbut-l-ene is a source of very hot a$-dimethallyl radicals. These allylic radi