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Thermal isomerization of dimethyl maleate

โœ Scribed by William W. Kwie; W.C. Gardiner Jr.

Book ID
104241841
Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
240 KB
Volume
4
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

EARLY experimental work on the kinetics of thermal cis -trans isomeriza--tions in the gas phase indicated that these reactions were typical uni-1 molecular processes . For three of these reactions, however, the tempera- ture dependence of the rate coefficients was reported to be anomalously small. Thus for the isomerizations of cis-2-butene2, dimethyl maleate and dimethyl citraconate4 respectively, frequency factors of 10ยฐ'3, 105'1

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## Abstract For Abstract see ChemInform Abstract in Full Text.