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Aminal-catalyzed isomerization of and addition to dimethyl maleate

✍ Scribed by A.Gilbert Cook; Andrea B Voges; Aster E Kammrath

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 178 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01595-7

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✦ Synopsis

The amine moiety of aminals adds to dimethyl maleate via azomethine ylid intermediates. The products of this reaction, in turn, cause dimethyl maleate to isomerize to dimethyl fumarate.

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