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Conjugate Addition of Nitroalkanes to Dimethyl Maleate. Regioselective Formation of Both Monoesters of 2-Alkylsuccinic Acids.

โœ Scribed by Roberto Ballini; Giovanna Bosica; Alessandro Palmieri; Marino Petrini; Claudio Pierantozzi


Publisher
John Wiley and Sons
Year
2003
Weight
155 KB
Volume
34
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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๐Ÿ“œ SIMILAR VOLUMES


Conjugate addition of nitroalkanes to di
โœ Roberto Ballini; Giovanna Bosica; Alessandro Palmieri; Marino Petrini; Claudio P ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 131 KB

Diesters of (E)-2-alkylidenesuccinic acids obtained by conjugate addition of nitroalkanes to dimethyl maleate can be selectively monohydrolyzed at the more reactive carboxyl group to the corresponding half-ester. Alternatively, total hydrolysis to the diacid allows a subsequent selective methyl este