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Thermal isomerization of 1,4,5,5-tetramethylcyclopentadiene

โœ Scribed by V. A. Mironov; A. P. Ivanov; A. A. Akhrem


Book ID
112421666
Publisher
Springer
Year
1972
Tongue
English
Weight
272 KB
Volume
21
Category
Article
ISSN
1573-9171

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โœ Jorge Daniel Perez; Daniel A. Wunderlin ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 324 KB

The gas phase thermal isomerization of 4-acetyl-5-methyl-isoxazole affords 3-cyano-2,4-pentanedione as the only product in good agreement with previous proposed isomerization mechanism for isoxazoles. On the other hand, kinetic parameters and MO theoretical calculations do not agree with those previ