Thermal Effects and Free-Energy Barrier Differences in the Ion Selectivity Mechanism of KcsA
β Scribed by Ngo, Van; Stefanovski, Darko; Farley, Robert; Haas, Stephan
- Book ID
- 122812714
- Publisher
- Biophysical Society
- Year
- 2013
- Tongue
- English
- Weight
- 40 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0006-3495
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The monoanion of 2-chloropentylphosphonic acid was thermally decomposed in the solid state, and the products of the fragmentation were identified and quantitatively determined. The reaction can involve either the elimination of HCl or the Cl ion and the metaphosphate (HPO 3 ), and it was found that
Thermal Fragmentation of 2-Chloropentylphosphonic Salts in the Solid State. Counter-Ion Effects on Reactivity and Selectivity. -The nature of the counter ion is found to strongly influence the chemoselectivity, i.e. cleavage of the P-C [β (II)] vs. cleavage of a C-H bond [β (III)/(IV)], of the therm