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Chemical free energies of solvation of single ions in different solvents and the hard-soft classification

✍ Scribed by F. Lohmann

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
187 KB
Volume
2
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES

Solvation of ionsβ€”XX. The ferroceneβ€”ferr
Solvation of ionsβ€”XX. The ferroceneβ€”ferricinium couple and its role in the estimation of free energies of transfer of single ions
✍ John W. Diggle; A.J. Parker πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 English βš– 520 KB

The ferrocene-ferricinium electrode (Pt/Foc. Fit') was investigated in water, acetonitrile, ethanol. DMSO and DMF using single scan cyclic voltammetry and phase sensitive ac polarography. The oxidation-reduction is pseudo-reversible in all five solvents with an electrochemical rate constant of appro