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Thermal Diffusion in CHBr2·CHBr2 - CHCl2 - CHCl2 solutions

✍ Scribed by J.C. Legros; W.A. Van Hook; G. Thomaes

Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
128 KB
Volume
2
Category
Article
ISSN
0009-2614

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Convection and thermal diffusion in a so
Convection and thermal diffusion in a solution heated from below II. the system CHBr2·CHBr2 - CHCl2·CHCl2
✍ J.C. Legros; W.A. Van Hook; G. Thomaes 📂 Article 📅 1968 🏛 Elsevier Science 🌐 English ⚖ 178 KB

The critical point for the onset of convection (BBnard point) was determined for the system CHBrZGHBr2 -CHCl2XHC12. No stabilizing effect was observed. Experiments which sampled this and a conventional thermal diffusion cell (cf. following letter) to directly measure the concentration gradient due t

Rate constants for the reaction of O(3P)
Rate constants for the reaction of O(3P) atoms with CH2 = CHF, CH2 = CHCl, and CH2 = CHBr at 298 ± 2°K
✍ R. Atkinson; J. N. Pitts JR. 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 298 KB 👁 1 views

Absolute rate constants for the reaction of O(3P) atoms with CHI = CHF, CH2 = CHC1, and CH2 = CHBr have been obtained at 298 f 2°K using a modulation phase shift technique. The rate constants ( k z X lo-\* l./mole.sec) obtained are: CH2 = CHF (1.61 =t 0.20), CH2 = CHCl (2.54 + 0.26), and CHZ = CHBr