## Abstract The gasβphase thermal decomposition rate of peroxyβ__n__βbutyryl nitrate (__n__βC~3~H~7~C(O)OONO~2~, PnBN) has been measured at ambient temperature (296 K) and 1 atm of air relative to that of peroxyacetyl nitrate (CH~3~C(O)OONO~2~, PAN) using mixtures of PAN (14β19 ppb), PnBN (22β46 pp
Thermal decomposition rate constant of peroxybenzoyl nitrate in the gas phase
β Scribed by Ohta, Tomohiro.; Mizoguchi, Isao.
- Book ID
- 127175711
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 486 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0013-936X
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π SIMILAR VOLUMES
## Abstract The bimolecular rate constant of __k__ (9.4 Β± 2.4 Γ 10^β12^ cm^3^ molecule^β1^ s^β1^ was measured using the relative rate technique for the reaction of the nitrate radical (NO~3~β’) with 4β(2,6,6βtrimethylβ1βcyclohexenβ1βyl)β3βbutenβ2βone (Ξ²βionone) at (297 Β± 3) K and 1 atmosphere total
s-Butoxy radicals have been generated by reacting fluorine with s-butanol: Over the temperature range 398.6 to 493.3 K the s-butoxy radical decomposes by two different pathways to yield acetaldehyde and propionaldehyde, acetaldehyde being the major product: (1) The ratio k , / k z was found to be