Thermal decomposition of trimethylene sulfone and 3-methyl sulfolane

✍ Scribed by Douglas Cornell; W. Tsang

• Book ID: 102445007
• Publisher: John Wiley and Sons
• Year: 1975
• Tongue: English
• Weight: 352 KB
• Volume: 7
• Category: Article
• ISSN: 0538-8066
• DOI: 10.1002/kin.550070602

✦ Synopsis

Abstract

Trimethylene sulfone and 3methyl sulfolane have been pyrolyzed using a modification of the toluene flow method and a comparative rate technique. The main decomposition reactions are
equation image
where k~1~=10^16.1±0.3^ exp(−28,100±500/T) sec^−1^ and k~2~=10^16.1±0.4^ exp(−33,200±750/T) sec^−1^.