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Thermal decomposition of methyl α-d-glycopyranosides

✍ Scribed by G.D. McGinnis; S. Parikh


Book ID
108308927
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
438 KB
Volume
31
Category
Article
ISSN
0008-6215

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The anomerization reactions of permethylated methyl o-glycopyranosides in the presence of various Lewis acid catalysts, such as Me,SiOTf, Me,SiOMs, BF,.OEt,, or TiCI, were examined in dichloromethane solution. p Anomers of the glycosides anomerized to the (Y anomer very rapidly, but the anomerizatio