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Thermal decomposition of anomeric glycopyranosides

✍ Scribed by Frank H. Hengemihle; Gary D. McGinnis; Shawn Prince; Curry Templeton

Book ID
104175678
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
443 KB
Volume
6
Category
Article
ISSN
0165-2370

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✍ Chang Kiu Lee; Eun Ju Kim; In-Sook Han Lee πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 677 KB

The anomerization reactions of permethylated methyl o-glycopyranosides in the presence of various Lewis acid catalysts, such as Me,SiOTf, Me,SiOMs, BF,.OEt,, or TiCI, were examined in dichloromethane solution. p Anomers of the glycosides anomerized to the (Y anomer very rapidly, but the anomerizatio