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Thermal decomposition of cyclopentane and related compounds

✍ Scribed by Wing Tsang

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
768 KB
Volume
10
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Cyclopentane has been decomposed in comparative‐rate single‐pulse shock‐tube experiments. The pyrolytic mechanism involves isomerization to 1‐pentene and also a minor pathway leading to cyclopropane and ethylene. This is followed by the decomposition of 1‐pentene and cyclopropane. The rate expressions over the temperature range of 1000°–1200Β° K are

Details of the cyclopentane decomposition processes are considered, and it appears that if the trimethylene radical is an intermediate, then Ξ”__H__~f~(trimethylene) ≀ 280 kJ/mol at 300Β°K.

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