𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Polar Effects in Decomposition of Peroxidic Compounds and Related Reactions

✍ Scribed by Sung Soo Kim


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.


πŸ“œ SIMILAR VOLUMES


Hydrogen abstraction from organosilicon
✍ J. A. Kerr; D. M. Timlin πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 634 KB

The photolysis of 1,1,3,3-tetrafluoroacetone has been reinvestigated as a source of CHFz radicals at temperatures up to 578'K, and the following rate constant ratio was determined for the reactions (8) (7) 2CHF2 -+ CHFzCHFz\* CHFz + CHFzCOCHFz -+ CHzFz + CF~COCHFZ log (k~/k~1'2)(mole-1'zcc1'2sec-1'2

Separation of polar and enthalpy effects
✍ KΓ‘roly HΓ©berger; Antal Lopata; J. Cs. JΓ‘szberΓ©nyi πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 87 KB πŸ‘ 2 views

Rate constants (k) of radical addition reactions between 15 carbon-and sulfur-centered radicals and 15 vinyl-type alkenes were collected from the literature. Three descriptor variables {a polar (Hammett) sigma scale [s(H)] and two radical sigma scales as defined by Creary and co-workers [s Á (C)] an