## Abstract The thermal decomposition of trifluoromethoxycarbonyl peroxy nitrate, CF~3~OC(O)O~2~NO~2~, has been studied between 278 and 306 K at 270 mbar total pressure using He as a diluent gas. The pressure dependence of the reaction was also studied at 292 K between 1.2 and 270 mbar total pressu
Thermal Decomposition of CF 3 O 2 NO 2
β Scribed by Mayer-Figge, A.; Zabel, F.; Becker, K. H.
- Book ID
- 118005789
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 351 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0022-3654
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Haloacetyl peroxynitrates are intermediates in the atmospheric degradation of a number of haloethanes. In this work, thermal decomposition rate constants of CF3C(0)02N02, CClFzC(0)02N02, CC12FC(0)02N02, and CC13C(0)02N02 have been determined in a temperature controlled 420 1 reaction chamber. Peroxy
A pulse radiolysis technique has been used to measure a rate constant of (6.6f 1.3) x lo-r2 cm3 molecule-' s-i for the association reaction between CF3C(0)02 radicals and NO2 at 295 K and one atmosphere total pressure of SF, diluent. A FAIR/ smog chamber system was used to study the thermal decompos