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Thermal Decomposition of 3,3'-Bis-Azidomethyl-Oxetane

✍ Scribed by Lee, Young Joo; Tang, Ching-Jen; Kudva, Gautam; Litzinger, Thomas A.


Book ID
120320080
Publisher
American Institute of Aeronautics and Astronautics
Year
1998
Tongue
English
Weight
275 KB
Volume
14
Category
Article
ISSN
0748-4658

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The quasi-living cationic copolymerization of 3,3-bis(chloromethyl)oxetane (BCMO) and -caprolactone (-CL), using boron trifluoride etherate as catalyst and 1,4-butanediol as coinitiator, was investigated in methylene chloride at 0Β°C. The resulting hydroxyl-ended copolymers exhibit a narrow molecular