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3,3-Bis(methylnitraminomethyl)oxetane (I) and 3,3-bis(nitratomethyl)oxetane (II)

✍ Scribed by George, C. ;Gilardi, R.

Book ID
114503577
Publisher
International Union of Crystallography
Year
1986
Tongue
English
Weight
459 KB
Volume
42
Category
Article
ISSN
0108-2701

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The anomalously large splitting and low intensity of vas(NO2) in solid 3,3-bis(nitratomethyl)oxetane, O(CH2)2C(CH2ONO2)2, is attributed to the effects of vibrational coupling based on a variable temperature study of the internal modes. In acetone-d6 solution conformational isomer equilibria involvin