Thermal Decomposition of 2-Fluoroethanol: Single Pulse Shock Tube and ab Initio Studies
β Scribed by Rajakumar, B.; Reddy, K. P. J.; Arunan, E.
- Book ID
- 125477705
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 145 KB
- Volume
- 107
- Category
- Article
- ISSN
- 1089-5639
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## Abstract 1,1,2,2βTetramethylcyclopropane (TTMC) has been decomposed in a singleβpulse shock tube. The main reaction process is magnified image Side reactions are unimportant. From comparative rate experiments (with cyclohexene decomposition as standard) the rate expression for these reactions ar
The pyrolysis of 2,2-dichloro-l , 1 ,I-trifluoroethane was studied over the temperature range of 112(tI26OoK at total reflected shock pressures from -2800 to 3100 torr. Below 1260"K, the decomposition leads to three reaction products which were identified as CF&FCI, CF&FH, and CF3CC13. The results a