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Thermal decomposition of 1,1,2,2-tetramethylcyclopropane in a single-pulse shock tube

✍ Scribed by Wing Tsang

Publisher: John Wiley and Sons
Year: 1973
Tongue: English
Weight: 525 KB
Volume: 5
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550050415

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✦ Synopsis

Abstract

1,1,2,2‐Tetramethylcyclopropane (TTMC) has been decomposed in a single‐pulse shock tube. The main reaction process is magnified image Side reactions are unimportant. From comparative rate experiments (with cyclohexene decomposition as standard) the rate expression for these reactions are

These numbers are consistent with a «best» value for cyclohexene decomposition of

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