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Thermal cyclisation of an alleneamidine to a dihydropyridine derivative involving a 1,5-hydrogen shift

✍ Scribed by R. Fuks; R. Merenyi; H. G. Viehe


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
118 KB
Volume
85
Category
Article
ISSN
0037-9646

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ChemInform Abstract: A Type 1 Intramolec
✍ Aberdeen Allen Jr.; Dana M. Gordon 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB

Intervention of a Thermal [1,5] Hydrogen Shift. -Heating a solution of (Ia) in toluene does not afford the desired intramolecular Diels-Alder adduct, however itaconate (IIa) is isolated. An analogous thermal [1,5] hydrogen shift takes place in three structurally related alkenyl maleates. -(ALLEN JR.