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ChemInform Abstract: A Type 1 Intramolecular Diels—Alder Approach to the Mniopetals: Intervention of a Thermal [1,5] Hydrogen Shift.

✍ Scribed by Aberdeen Allen Jr.; Dana M. Gordon

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199941038

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✦ Synopsis

Intervention of a Thermal [1,5] Hydrogen Shift. -Heating a solution of (Ia) in toluene does not afford the desired intramolecular Diels-Alder adduct, however itaconate (IIa) is isolated. An analogous thermal [1,5] hydrogen shift takes place in three structurally related alkenyl maleates. -(ALLEN JR.,

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