Thermal and photochemical Wallach rearrangement of azoxybenzene in zeolite cages
✍ Scribed by A Lalitha; K Pitchumani; C Srinivasan
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 159 KB
- Volume
- 160
- Category
- Article
- ISSN
- 1381-1169
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
We wish to report direct evidence for a homolytic scission-recombination mechanism in the thermal eMeisenheimer" rearrangement' of the title compound, I, to the hydroxylamine, II (equation I). This mechanism W&B apparently first proposed by Schgllkopf,3 who adduced threefold
## Abstract The activation parameters of the thermal rearrangements of the __trans__‐divinylcyclopropanes **1** and **2**, and of __cis__‐divinylcyclopropane **3** to give cycloheptadiene **5** have been determined. In addition it has been shown that __trans__‐divinylcyclopropane‐cycloheptadiene re