Thermal and photochemical cyclisation of 2-methyl-3-(pent-4-enyl)-cyclohex-2-en-1-one
✍ Scribed by R. Ramage; A. Sattar
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 169 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.004 A Ê R factor = 0.056 wR factor = 0.146 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 15 H 17 NO 2 , the six-membered cyclohexene ring has an envelope conformation. The structure is stabilized by O-HÁ Á ÁN hydrogen bonds and weak van der Waals interactions. There are no C-HÁ Á Á orinteractions between the two ring systems; however, there is an intermolecular
In the structure of the title compound, C 22 H 24 N 2 O 3 , short intermolecular CÐHÁ Á ÁO contacts in¯uence the crystal packing and molecular ladders are formed. Intramolecular NÐHÁ Á ÁO hydrogen bonds make the Z con®guration stable by formation of six-membered rings.
## Abstract For Abstract see ChemInform Abstract in Full Text.