The NH unit on the exocyclic C C double bond in the title compound, C 25 H 23 N 3 O, interacts with the carbonyl group through an intramolecular hydrogen bond.
(Z)-4-(4-{4-[(Z)-1-Methyl-3-oxobut-1-enylamino]phenoxy}phenylamino)pent-3-en-2-one
✍ Scribed by Feng, Yanhua ;Yin, Xianhong ;Chen, Lin ;Tan, Minyu ;Yu, Kaibei
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 172 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the structure of the title compound, C 22 H 24 N 2 O 3 , short intermolecular CÐHÁ Á ÁO contacts in¯uence the crystal packing and molecular ladders are formed. Intramolecular NÐHÁ Á ÁO hydrogen bonds make the Z con®guration stable by formation of six-membered rings.
📜 SIMILAR VOLUMES
The NH unit on the exocyclic C C double bond in the title compound, C 24 H 21 N 3 O, which is on the same side of the double bond as the C O unit of the pyrazolone ring, interacts with the carbonyl group through an intramolecular N-HÁ Á ÁO hydrogen bond [2.685 (2) A ˚].