Thermal addition of dibenzoylacetylene to cycloheptatriene and the photo-rearrangement of the thermal adduct
โ Scribed by S. Lahiri; V. Dabral; M.V. George
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- French
- Weight
- 742 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4020
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๐ SIMILAR VOLUMES
Nechanistic aspects of thermal sigmatropic rearrangements in cycloheptatrienes have been studied extensively.2 In contrast, the synthetic potential of these isomerization reactions has been exploited only recently. For example, a facile entry to tricyclo[4.3.1.03g8]decane (protoadamantane) derivativ
The thermal rearrangement of thionocarbamates of the formula R2N-C(=S)-0-Ar (I) into thiolcarbamates of the formula R2N-C(=O)-S-Ar (II) has recently been reported.lV2) This paper describes the kinetics of the rearrangement in order to elucidate the reaction mechanism.