The thermal rearrangement of thionocarbamates of the formula R2N-C(=S)-0-Ar (I) into thiolcarbamates of the formula R2N-C(=O)-S-Ar (II) has recently been reported.lV2) This paper describes the kinetics of the rearrangement in order to elucidate the reaction mechanism.
โฆ LIBER โฆ
The thermal rearrangement of phenylnitrene to cyanocyclopentadiene
โ Scribed by E. Hedaya; M.E. Kent; D.W. McNeil; F.P. Lossing; T. McAllister
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 305 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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IH the first paper\* of this series, the unusual cese of the Chugeer rea&ioll that pyrolysis causes rearrangement of zsnthstes to dithiolcsrbonstes with retention of configuration was reported. The perticipztim of nelghbm Srnqwsa founl. ueCessaryforthe reerrsnge mezt, because the resrrsqement tookpl