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Thermal (1,3)-allylic rearrangements in sulfoxides and sulfones

✍ Scribed by Raymond D. Baechler; Pamela Bentley; Lisa Deuring; Susan Fisk


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
326 KB
Volume
23
Category
Article
ISSN
0040-4039

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## Abstract Stereospecific ring opening of the sulfoxides __cis__‐13 and __trans__‐14 in refluxing toluene gave the corre sponding sulfenic acids 9, 10 intermediates respectively. The sulfenic acid 9 dimerized to the thiolsulfinate 17 by dual function of the sulfenic acid as __S__‐nucleophile/__S__