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Theory of titration curves : Points of minimum slope on potentiometric strong acid-strong base and precipitation titration curves

✍ Scribed by Louis Meites; James A. Goldman


Publisher
Elsevier Science
Year
1964
Tongue
English
Weight
597 KB
Volume
30
Category
Article
ISSN
0003-2670

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✦ Synopsis


This increnscs the cxtcnt of clissocintion in the original solution: if K. is much lnrgcr than Ifto* the incrcrrsc will bc so cxtcnsivc that the titration curve will assume the form of that for II "strong" (i.c., cswntially complctcly clissociatccl) acid. If ICo is comparable to or smollcr than I<,4 the degree of dissocintion appronchcs LI limiting vduc much lower than I as the dilution incrcascs. Anal. Ciriwa. Rctu, 30 (IgQ) 200-208~ THEORY Or? TITRATION CURVES. Iv 201 ' 1,. ;Mlr1?1rS AND J. A. GOLDMAN, Awril.


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Theory of titration curves: Locations of
✍ Louis Meites; James A Goldman πŸ“‚ Article πŸ“… 1964 πŸ› Elsevier Science 🌐 English βš– 687 KB

## AKALYTICA CHIMICA ACTA alcncc point in a titration of this type cvcn thougli it c,an never do so in the "symmctrical" (isovalcnt) case. DERIVATION 01: A GIINElCAL EQUA'IIOX I:011 'THE 1KI~LEC'I'ION I'OIN'I' We shall consiclcr the general precipitation reaction ~Ilv"+ -1.. m:\~~-= l$,,A,, (I) +