Theory of titration curves: Part VI The slopes and inflection points of potentiometric chelometric titration curves
β Scribed by Louis Meites; Thelma Meites
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 831 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0003-2670
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π SIMILAR VOLUMES
## AKALYTICA CHIMICA ACTA alcncc point in a titration of this type cvcn thougli it c,an never do so in the "symmctrical" (isovalcnt) case. DERIVATION 01: A GIINElCAL EQUA'IIOX I:011 'THE 1KI~LEC'I'ION I'OIN'I' We shall consiclcr the general precipitation reaction ~Ilv"+ -1.. m:\~~-= l$,,A,, (I) +
This increnscs the cxtcnt of clissocintion in the original solution: if K. is much lnrgcr than Ifto\* the incrcrrsc will bc so cxtcnsivc that the titration curve will assume the form of that for II "strong" (i.c., cswntially complctcly clissociatccl) acid. If ICo is comparable to or smollcr than I<,