Theory of the electron diffraction study of triatomic molecules, characterized by large amplitudes of the vibrations
โ Scribed by V. I. Bazhanov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1984
- Tongue
- English
- Weight
- 574 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0022-4766
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Ddfractmn data on Baize analyzed by a new approach, mdlcate an anhz.rmomc otentlal wth il barrier of 71(12) cm-\* at a hnear geometry The structural and vlbratlonal parameters were found to be &No) = 3 150(7)A,~&k~I= 148.0(9)a, .f, = 0 69 (8) mdyn/A, &, = 0 14(6) mdyn/A, k~ = -0 0075(15) mdyn/A, kg
A dynamIca: model IS developed appropnate for symmetric tnatomlc molecules with large-amphtude bendmg motion The total hamdtoruan IS separated mto rotation-bendmg and stretching parts The bendmg potent& LS approximated by a quartw-harmonic functmn. In the denvatmn of the mten=\*+\_J equntlon a curvl
The molecular dimensions of silyl isocyanate and isothiocyanate have been determined in the vapor phase by the sector-microphotomater method of electron diffraction. The large amplitude Si-N-C deformations are analysed in terms of possible potential functions