Electron diffraction study of molecules with large-amplitude motion
β Scribed by J.H.M. Ter Brake; F.C. Mijlhoff
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 232 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
A dynamIca: model IS developed appropnate for symmetric tnatomlc molecules with large-amphtude bendmg motion The total hamdtoruan IS separated mto rotation-bendmg and stretching parts The bendmg potent& LS approximated by a quartw-harmonic functmn. In the denvatmn of the mten=\*+\_J equntlon a curvl
The molecular dimensions of silyl isocyanate and isothiocyanate have been determined in the vapor phase by the sector-microphotomater method of electron diffraction. The large amplitude Si-N-C deformations are analysed in terms of possible potential functions