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Theory of kinetic salt effects in diffusion-controlled reactions. Part 1.?Reactions between ions with equilibrium ion atmospheres

โœ Scribed by Logan, S. R.


Book ID
121451268
Publisher
Royal Society of Chemistry
Year
1966
Weight
546 KB
Volume
62
Category
Article
ISSN
0014-7672

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Reactions of p-nitrophenyl diphenyl phosphinate (p-NPDP) with OH- and F- are inhibited by micelles of dodecyl polyoxyethylene ethers C12E10 and C12E23. Rate constants decrease sharply in very dilute surfactant and become approximately constant as p-NPDP becomes fully micellar bound, with inhibition