Kinetics of reactions in heterocycles. Part X. Reactions of substituted N-methylpyridinium salts with hydroxide ions
โ Scribed by Barlin, Gordon B.; Benbow, John A.
- Book ID
- 119938056
- Publisher
- Royal Society of Chemistry
- Year
- 1974
- Tongue
- English
- Weight
- 930 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1472-779X
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๐ SIMILAR VOLUMES
Secondary ion mass spectra of N-methylpyridinium halides (C'X-, where C+ is a pyridinium cation and Xis a halogen anion) exhibit the C + ions, a series of cluster ions ((C+),,(X-),,-,) and, furthermore, remarkable [ CX -R I + ions (R = H or Me). The mechanism of the formation of [ CX -R] + ions was
Reactions of p-nitrophenyl diphenyl phosphinate (p-NPDP) with OH- and F- are inhibited by micelles of dodecyl polyoxyethylene ethers C12E10 and C12E23. Rate constants decrease sharply in very dilute surfactant and become approximately constant as p-NPDP becomes fully micellar bound, with inhibition