✦ LIBER ✦

Theory of electrophoretic mobility of polyelectrolyte chains

✍ Scribed by Murugappan Muthukumar

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 394 KB
Volume: 3
Category: Article
ISSN: 1022-1344
DOI: 10.1002/mats.1994.040030105

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

An explicit formula is derived for the electrophoretic mobility of a linear polyelectrolyte chain in terms of the molecular weight, Debye length and solvent quality. The nature of the crossover between different regimes as the salt concentration and molecular weight are varied is presented. The effect of chain statistics intermediate between the Gaussian and rodlike limits on the electrophoretic mobility is analysed for the first time.

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