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Electrophoretic Mobility of a Polyelectrolyte-Adsorbed Particle: Effect of Segment Density Distribution

✍ Scribed by Hiroyuki Ohshima


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
173 KB
Volume
185
Category
Article
ISSN
0021-9797

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✦ Synopsis


Varoqui's theory [Nouv. J. Chim. 6, 187 (1982)] for the electrophoretic mobility of a charged colloidal particle adsorbed by neutral polymers with an exponential distribution of the polymer segments is extended to the case where adsorbed polymers are charged. An analytic mobility expression is derived on the basis of the linearized Poisson-Boltzmann equation. Comparison is made with the case of particles coated with a polyelectrolyte layer of fixed thickness with uniform segment distribution.


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Electrophoretic Mobility of a Particle C
✍ Jyh-Ping Hsu; Yang-Pu Fan πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 388 KB

The electrophoretic mobility of a particle coated with an ionpenetrable charged membrane in a uniform electric field is investigated. In particular, the effects of the distribution of fixed charges and that of the dielectric constant in the membrane phase on the electrophoretic mobility are investig