Theory of bond failure in hydrogen-bonded solids
β Scribed by D.R. Axelrad
- Publisher
- Elsevier Science
- Year
- 1979
- Weight
- 750 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0378-4487
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β¦ Synopsis
A theory of bond failure for a class of hydrogen bonded solids is developed on the basis of probabilistic mechanics . The proposed models for bond dissociation show the applicability of the theory of Markov processes in which the most significant quantity in the representation of such processes is the transition probability . From a phenomenological point of view this quantity is shown to be equivalent to a "rate constant" characterizing the deterministic process of bond dissociation .
π SIMILAR VOLUMES
## Abstract The βhydrogen bondβ or βhydrogen bridgeβ concept has proved to be one of the most useful structural concepts in modern science. The properties of substances containing hydrogen bonds depend on the strength, symmetry, and polarity of these bonds. These characteristics, in turn, are relat
The hydrogen bond is the most important of all directional intermolecular interactions. It is operative in determining molecular conformation, molecular aggregation, and the function of a vast number of chemical systems ranging from inorganic to biological. Research into hydrogen bonds experienced a