## Abstract Recent experiments indicate that the number of hydrogen bonds in solutions increases in the critical region of the solvent. This effect can be explained by the density fluctuations near the critical point. A theory of this unusual effect is developed. The theoretical predictions are com
Theory of hydrogen bonding in supercritical fluids
β Scribed by Ram B. Gupta; Constantinos G. Panayiotou; Isaac C. Sanchez; Keith P. Johnston
- Publisher
- American Institute of Chemical Engineers
- Year
- 1992
- Tongue
- English
- Weight
- 969 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0001-1541
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π SIMILAR VOLUMES
A detailed analysis of hydrogen bonding in supercritical water is made from Monte Carlo simulations along the 773 K isotherm over a wide range of pressures from 10 to 10000 MPa. It is shown that an energetic definition of H-bonding is much more effective in separating H-bonded and non-bonded molecul
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract The βhydrogen bondβ or βhydrogen bridgeβ concept has proved to be one of the most useful structural concepts in modern science. The properties of substances containing hydrogen bonds depend on the strength, symmetry, and polarity of these bonds. These characteristics, in turn, are relat