Theoritical study on an anomalous isotopic effect on the position and integrated intensity of the ir stretching vibration band for medium-strong and strong hydrogen bonds

On an anomalous isotopic effect for the

On an anomalous isotopic effect for the AH stretching vibrational frequency in strong hydrogen bonds AH…B

✍ V.A. Savel'ev; N.D. Sokolov 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 327 KB

A theoretical investigation has been made of the nature of the u(AH) stretching frequency change in A-H...B hydrogea bonds on the substitution of D for H. An explanation of the correhtion between the c(AH)/u(AD) isotope effect and the Utah) frequency and also between u(AH)/u(AD) and the isotopic cha