Theoretical Study on the Mechanism of Iron Carbonyls Mediated Isomerization of Allylic Alcohols to Saturated Carbonyls
✍ Scribed by Vicenç Branchadell; Christophe Crévisy; René Grée
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 178 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
The mechanism of isomerization of allyl thiocyanate to allyl isothiocyanate has been investigated both experimentally and theoretically. The kinetic study indicates that the reaction is unimolecular and is not ionic. The entropy of activation suggests strongly that the mechanism involves a cyclic tr
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
13C and 17O chemical shifts and 55Mn,13C coupling constants of nine pentacarbonylmanganese complexes (6È14), 13 tetracarbonylmanganese complexes (15È27) and Ðve tetra-RMn(CO) 5 RMn(CO) 4 PR 3 @ carbonylmanganacycle complexes (1aÈe) were determined and are discussed in terms of p-inductive substituen