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Theoretical study on the kinetics and the mechanism for the gas-phase reaction of 1-naphtylmethyl radical with molecular oxygen

โœ Scribed by Oguchi, Tatsuo; Murakami, Yoshinori

Book ID
122077298
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
871 KB
Volume
585
Category
Article
ISSN
0009-2614

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Kinetics and mechanism of the reaction o
Kinetics and mechanism of the reaction of vinyl radicals with molecular oxygen
โœ Jong-Yoon Park; Michael C. Heaven; David Gutman ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 501 KB

The kinetics and mechanism of the gaseous reaction of vinyl radicals with molecular oxygen have been studied at 296 K. The products formed are HCO and H2C0. The rate constant is 1.0 X 10-r' cm3 molecule-' s-\* and is independent of pressure between 0.4 and 4 Torr.