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Theoretical study of the sign of the 1J(15N15N) indirect nuclear spin-spin coupling constant

✍ Scribed by V. Galasso

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 228 KB
Volume: 145
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)80003-4

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✦ Synopsis

Non-empirical calculations using the equations-of-motion approach are reported for iJ( 15Nt5N) in hydrazine, diazene, isodiazene, the azide anion, and nitrogen. Irrespective of the single or multiple nature of the bond between the nitrogens, iJ( isNi5N) should be negative in all compounds. The only exception is found in the transoid arrangements of hydrazine.

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