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Theoretical study of the molecular ions SiH−5 and SiH−3

✍ Scribed by Frerich Keil; Reinhart Ahlrichs


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
621 KB
Volume
8
Category
Article
ISSN
0301-0104

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I3he molecuIar structures of SiI-&N3 and (Sti3)2NCN have been detern&d by electron diffraction: Sii-I~Ns has a non-lincti SiNs skeleton, and (S~HJ)~NCN is a carbodiimide with SiNCKSi probably linear. A new model is pro-p&d which rationaLises the observed geome!ry of a number of molecu&r pseudohalide